FOOD CHEMISTRY

Oxidation in food: Why foods turn brown and go rancid

Quick Takeaway

Understanding the chemical process of oxidation and how it affects food quality, color, and nutritional value.

Quick Takeaway: Oxidation occurs when oxygen reacts with food molecules, causing browning, rancidity, and nutrient loss. Antioxidants and proper storage can slow this process.

What is Oxidation?

Oxidation is a chemical reaction where: - Oxygen gains electrons from food molecules - Food molecules lose electrons and become unstable - Free radicals form that can damage other molecules - Chain reactions occur that accelerate the process

Types of Food Oxidation

- Enzymatic browning: Polyphenol oxidase + oxygen (apples, potatoes) - Lipid oxidation: Fats + oxygen (rancid oils, butter) - Protein oxidation: Proteins + oxygen (meat discoloration) - Vitamin oxidation: Vitamins + oxygen (nutrient loss)

Factors Affecting Oxidation

- Oxygen exposure: More oxygen = faster oxidation - Temperature: Higher temps = faster reactions - Light: UV light accelerates oxidation - Metals: Iron and copper catalyze oxidation - pH: Acidic conditions slow some oxidation

Preventing Oxidation

- Antioxidants: Vitamin C, E, polyphenols block free radicals - Vacuum sealing: Removes oxygen from packaging - Refrigeration: Slows chemical reactions - Acid treatment: Lemon juice on cut fruits - Blanching: Destroys enzymes that cause browning

Common Examples

- Cut apples: Turn brown due to enzymatic oxidation - Rancid butter: Lipid oxidation creates off-flavors - Stale nuts: Lipid oxidation makes them taste bitter - Faded vegetables: Oxidation destroys pigments

Beneficial Oxidation

Some oxidation is desirable: - Aging meat: Controlled oxidation develops flavor - Wine aging: Oxidation creates complex flavors - Cheese ripening: Oxidation develops characteristic tastes - Tea processing: Oxidation creates different tea types

Storage Tips

- Refrigerate: Slows oxidation reactions - Use airtight containers: Limits oxygen exposure - Add antioxidants: Lemon juice, vitamin C - Avoid light: Store in dark places - Use quickly: Fresh foods have less oxidation

Oxidation in food: Why foods turn brown and go rancid
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